Polymer Solar Cells With Inkjet-Printed Doped-PEDOT: PSS Anode
Identifieur interne : 000690 ( Main/Repository ); précédent : 000689; suivant : 000691Polymer Solar Cells With Inkjet-Printed Doped-PEDOT: PSS Anode
Auteurs : RBID : Pascal:14-0060265Descripteurs français
- Pascal (Inist)
- Cellule solaire organique, Encre, Styrènesulfonate polymère, Anode, Conductivité électrique, Transparence, Hétérojonction, Traitement surface, Traitement par plasma, Relation mise en oeuvre propriété, Morphologie, Dépôt centrifugation, Ozonation, Caractéristique courant tension, Etude expérimentale, Polymère conducteur, Thiophène dérivé polymère, Polyélectrolyte, Propriété électrique, Propriété optique, Polymère aromatique, Ethylènedioxythiophène polymère, Thiophène(3-hexyl) polymère.
English descriptors
- KwdEn :
- Anode, Aromatic polymer, Conducting polymers, Electrical conductivity, Electrical properties, Experimental study, Heterojunction, Ink, Morphology, Optical properties, Organic solar cells, Ozonization, Plasma assisted processing, Polyelectrolyte, Property processing relationship, Spin-on coating, Styrenesulfonate polymer, Surface treatment, Thiophene derivative polymer, Transparency, Voltage current curve.
Abstract
In this article, we describe the development of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PED OT:PSS)-based ink for the fabrication of indium tin oxide (ITO)-free polymer solar cells (PSCs). The ink consisted of PEDOT:PSS, suitably doped with dimethyl sulfoxide (DMSO) in solution. The printed PEDOT:PSS showed electrical conductivity of 1000 S/cm and transparency around 85% in the visible range. Then, they were employed as anodes in ITO-free polymer PSCs based on a bulk heterojunction of poly(3-hexylthiophene) and [6,6]-phenyl C61-butyricacid methyl ester. The effects of surface treatments (O2 plasma, UV ozone) of glass substrates on the quality and morphology of the printed layer were investigated in order to improve the anode quality. The performances of the devices with printed polymeric anode were compared to the one realized depositing DMSO-PEDOT:PSS by spin coating technique. The best cells performances were obtained by UV ozone treatment reaching a power conversion efficiency of 1.5%.
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(Naples)</wicri:noRegion></affiliation></author><author><name sortKey="Grimaldi, Immacolata Angelica" uniqKey="Grimaldi I">Immacolata Angelica Grimaldi</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Portici (Naples)</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Physic & Science, University of Naples Federico II, Piazzale Tecchio</s1><s2>Naples</s2><s3>ITA</s3><sZ>3 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Naples</wicri:noRegion></affiliation></author><author><name sortKey="Loffredo, Fausta" uniqKey="Loffredo F">Fausta Loffredo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Portici (Naples)</wicri:noRegion></affiliation></author><author><name sortKey="Morvillo, Pasquale" uniqKey="Morvillo P">Pasquale Morvillo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Portici (Naples)</wicri:noRegion></affiliation></author><author><name sortKey="Villani, Fulvia" uniqKey="Villani F">Fulvia Villani</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Portici (Naples)</wicri:noRegion></affiliation></author><author><name sortKey="Minarini, Carla" uniqKey="Minarini C">Carla Minarini</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Italie</country><wicri:noRegion>Portici (Naples)</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">14-0060265</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 14-0060265 INIST</idno><idno type="RBID">Pascal:14-0060265</idno><idno type="wicri:Area/Main/Corpus">000136</idno><idno type="wicri:Area/Main/Repository">000690</idno></publicationStmt><seriesStmt><idno type="ISSN">0272-8397</idno><title level="j" type="abbreviated">Polym. compos.</title><title level="j" type="main">Polymer composites</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Anode</term><term>Aromatic polymer</term><term>Conducting polymers</term><term>Electrical conductivity</term><term>Electrical properties</term><term>Experimental study</term><term>Heterojunction</term><term>Ink</term><term>Morphology</term><term>Optical properties</term><term>Organic solar cells</term><term>Ozonization</term><term>Plasma assisted processing</term><term>Polyelectrolyte</term><term>Property processing relationship</term><term>Spin-on coating</term><term>Styrenesulfonate polymer</term><term>Surface treatment</term><term>Thiophene derivative polymer</term><term>Transparency</term><term>Voltage current curve</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Cellule solaire organique</term><term>Encre</term><term>Styrènesulfonate polymère</term><term>Anode</term><term>Conductivité électrique</term><term>Transparence</term><term>Hétérojonction</term><term>Traitement surface</term><term>Traitement par plasma</term><term>Relation mise en oeuvre propriété</term><term>Morphologie</term><term>Dépôt centrifugation</term><term>Ozonation</term><term>Caractéristique courant tension</term><term>Etude expérimentale</term><term>Polymère conducteur</term><term>Thiophène dérivé polymère</term><term>Polyélectrolyte</term><term>Propriété électrique</term><term>Propriété optique</term><term>Polymère aromatique</term><term>Ethylènedioxythiophène polymère</term><term>Thiophène(3-hexyl) polymère</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">In this article, we describe the development of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PED OT:PSS)-based ink for the fabrication of indium tin oxide (ITO)-free polymer solar cells (PSCs). The ink consisted of PEDOT:PSS, suitably doped with dimethyl sulfoxide (DMSO) in solution. The printed PEDOT:PSS showed electrical conductivity of 1000 S/cm and transparency around 85% in the visible range. Then, they were employed as anodes in ITO-free polymer PSCs based on a bulk heterojunction of poly(3-hexylthiophene) and [6,6]-phenyl C<sub>61</sub>-butyricacid methyl ester. The effects of surface treatments (O<sub>2</sub> plasma, UV ozone) of glass substrates on the quality and morphology of the printed layer were investigated in order to improve the anode quality. The performances of the devices with printed polymeric anode were compared to the one realized depositing DMSO-PEDOT:PSS by spin coating technique. The best cells performances were obtained by UV ozone treatment reaching a power conversion efficiency of 1.5%.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0272-8397</s0></fA01><fA02 i1="01"><s0>PCOMDI</s0></fA02><fA03 i2="1"><s0>Polym. compos.</s0></fA03><fA05><s2>34</s2></fA05><fA06><s2>9</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Polymer Solar Cells With Inkjet-Printed Doped-PEDOT: PSS Anode</s1></fA08><fA11 i1="01" i2="1"><s1>DE GIROLAMO DEL MAURO (Anna)</s1></fA11><fA11 i1="02" i2="1"><s1>DIANA (Rosita)</s1></fA11><fA11 i1="03" i2="1"><s1>GRIMALDI (Immacolata Angelica)</s1></fA11><fA11 i1="04" i2="1"><s1>LOFFREDO (Fausta)</s1></fA11><fA11 i1="05" i2="1"><s1>MORVILLO (Pasquale)</s1></fA11><fA11 i1="06" i2="1"><s1>VILLANI (Fulvia)</s1></fA11><fA11 i1="07" i2="1"><s1>MINARINI (Carla)</s1></fA11><fA14 i1="01"><s1>ENEA, UTTP-NANO, Piazzale Enrico Fermi 1</s1><s2>Portici (Naples)</s2><s3>ITA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Physic & Science, University of Naples Federico II, Piazzale Tecchio</s1><s2>Naples</s2><s3>ITA</s3><sZ>3 aut.</sZ></fA14><fA20><s1>1493-1499</s1></fA20><fA21><s1>2013</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>18916</s2><s5>354000501962460130</s5></fA43><fA44><s0>0000</s0><s1>© 2014 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>18 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>14-0060265</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Polymer composites</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>In this article, we describe the development of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PED OT:PSS)-based ink for the fabrication of indium tin oxide (ITO)-free polymer solar cells (PSCs). The ink consisted of PEDOT:PSS, suitably doped with dimethyl sulfoxide (DMSO) in solution. The printed PEDOT:PSS showed electrical conductivity of 1000 S/cm and transparency around 85% in the visible range. Then, they were employed as anodes in ITO-free polymer PSCs based on a bulk heterojunction of poly(3-hexylthiophene) and [6,6]-phenyl C<sub>61</sub>-butyricacid methyl ester. The effects of surface treatments (O<sub>2</sub> plasma, UV ozone) of glass substrates on the quality and morphology of the printed layer were investigated in order to improve the anode quality. The performances of the devices with printed polymeric anode were compared to the one realized depositing DMSO-PEDOT:PSS by spin coating technique. The best cells performances were obtained by UV ozone treatment reaching a power conversion efficiency of 1.5%.</s0></fC01><fC02 i1="01" i2="X"><s0>001D10A08</s0></fC02><fC02 i1="02" i2="X"><s0>001D06C02D1</s0></fC02><fC02 i1="03" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Cellule solaire organique</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Organic solar cells</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Encre</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Ink</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Tinta</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Styrènesulfonate polymère</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Styrenesulfonate polymer</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Estireno sulfonato polímero</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Anode</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Anode</s0><s5>04</s5></fC03><fC03 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tension</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Voltage current curve</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Característica corriente tensión</s0><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Experimental study</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>15</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>Polymère conducteur</s0><s5>31</s5></fC03><fC03 i1="16" i2="3" l="ENG"><s0>Conducting polymers</s0><s5>31</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Thiophène dérivé polymère</s0><s2>NK</s2><s5>32</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Thiophene derivative polymer</s0><s2>NK</s2><s5>32</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Tiofeno derivado polímero</s0><s2>NK</s2><s5>32</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Polyélectrolyte</s0><s5>33</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Polyelectrolyte</s0><s5>33</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Polielectrolito</s0><s5>33</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Propriété électrique</s0><s5>34</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Electrical properties</s0><s5>34</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Propiedad eléctrica</s0><s5>34</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Propriété optique</s0><s5>35</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Optical properties</s0><s5>35</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Propiedad óptica</s0><s5>35</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Polymère aromatique</s0><s5>36</s5></fC03><fC03 i1="21" i2="X" l="ENG"><s0>Aromatic polymer</s0><s5>36</s5></fC03><fC03 i1="21" i2="X" l="SPA"><s0>Polímero aromático</s0><s5>36</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Ethylènedioxythiophène polymère</s0><s4>INC</s4><s5>41</s5></fC03><fC03 i1="23" i2="X" l="FRE"><s0>Thiophène(3-hexyl) polymère</s0><s4>INC</s4><s5>42</s5></fC03><fN21><s1>076</s1></fN21></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>Conference on the Times of Polymers & Composites (TOP)</s1><s2>6</s2><s3>Ischia ITA</s3><s4>2012-06-10</s4></fA30></pR></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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